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Lewis Acid Activated AzaDiels–Alder Reaction of N3Pyridylaldimines: An Experimental and Computational Study
- Source :
- European Journal of Organic Chemistry; April 2010, Vol. 2010 Issue: 11 p2091-2099, 9p
- Publication Year :
- 2010
-
Abstract
- A combined theoretical and experimental study of a Povarovtype cycloaddition reaction suggests an asynchronous concerted process that is favored by double Lewis acid activation with BF3·Et2O; endoselectivity was observed in the reactions between N3pyridylaldimines and styrene, cyclopentadiene, or indene, and substituted tetrahydro1,5naphthyridine derivatives were obtained in a regio and stereoselective fashion.
Details
- Language :
- English
- ISSN :
- 1434193X and 10990690
- Volume :
- 2010
- Issue :
- 11
- Database :
- Supplemental Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs21002489
- Full Text :
- https://doi.org/10.1002/ejoc.200901325