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A new method for the synthesis of substituted indeno1,2bthiophene with subsequent ring expansion to form substituted thieno3,2cquinoline

Authors :
Castle, Lyle W.
Elmaaty, Tarek Abou
Source :
Journal of Heterocyclic Chemistry; May 2006, Vol. 43 Issue: 3 p629-631, 3p
Publication Year :
2006

Abstract

2Phenacylindan1,3dione 3 was treated with Lawessons reagent 2,4bis4methoxyphenyl1,3dithia2,4diphosphetane2,4disulfide to form 2phenyl4Hindeno1,2bthiophene4one 4. Compound 4was subsequently reacted with hydroxyl amine to form the oxime 5, which, upon treatment with polyphosphoric acid, underwent ring expansion Beckmann rearrangement to give 2phenylthieno3,2cquinoline45Hone.

Details

Language :
English
ISSN :
0022152X and 19435193
Volume :
43
Issue :
3
Database :
Supplemental Index
Journal :
Journal of Heterocyclic Chemistry
Publication Type :
Periodical
Accession number :
ejs21009611
Full Text :
https://doi.org/10.1002/jhet.5570430316