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Unprecedented Solution‐Stable Silver(I) Ethynediyl Clusters
- Source :
- Chemistry - A European Journal; November 2010, Vol. 16 Issue: 41 p12321-12323, 3p
- Publication Year :
- 2010
-
Abstract
- Rise of the silver surfer: A novel solution‐stable silver ethynediyl complex [Ag7(C2)(CF3CO2)5(bpy)5]⋅MeCN⋅0.5 MeOH (bpy=2,2′‐bipyridine) was prepared by reacting Me3SiCCH with [Ag(bpy)CF3CO2] in methanol (see figure). This complex represents the first example of a solution‐stable silver ethynediyl cluster, and it is yellow emissive in MeCN/MeOH at 77 K.
Details
- Language :
- English
- ISSN :
- 09476539 and 15213765
- Volume :
- 16
- Issue :
- 41
- Database :
- Supplemental Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Periodical
- Accession number :
- ejs22693757
- Full Text :
- https://doi.org/10.1002/chem.201001985