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β-Acarbose. III. The Attempted Alkylation of a 1-Epivalienamine Derivative with Various Carbohydrate Triflates

Authors :
McAuliffe, Joseph C.
Stick, Robert V.
Source :
Australian Journal of Chemistry; 1997, Vol. 50 Issue: 3 p203-208, 6p
Publication Year :
1997

Abstract

Various carbohydrate triflates have been treated with cyclohexylamine and a 1-epivalienamine derivative to give some of the desired secondary amine, but mainly the product of a competing elimination reaction, namely a mixture of alkenes. When the reactions were conducted in the presence of potassium carbonate, novel carbohydrate carbamates were formed.

Details

Language :
English
ISSN :
00049425 and 14450038
Volume :
50
Issue :
3
Database :
Supplemental Index
Journal :
Australian Journal of Chemistry
Publication Type :
Periodical
Accession number :
ejs23965798
Full Text :
https://doi.org/10.1071/C96153