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{3,3′‐[2,2′‐(Ethylenedioxy)dibenzylidene]bis(S‐methyl dithiocarbazate)}nickel(II)
- Source :
- Acta Crystallographica Section C: Crystal Structure Communications; May 2001, Vol. 57 Issue: 5 p523-525, 3p
- Publication Year :
- 2001
-
Abstract
- The tetradentate N2S2Schiff base ligand 3,3′‐[2,2′‐(ethyl­ene­di­oxy)di­benzyl­idene]­bis­(S‐methyl di­thio­car­ba­zate) (H2L), prepared by the condensation of S‐methyl di­thio­carb­aza­te with 1,4‐bis(2‐formyl­phenyl)‐1,4‐dioxa­butane in a 1:2 molar ratio, reacts with nickel acetate to form the title neutral metal complex, [Ni(C20H20N4O2S4)]. The X‐ray structure of the complex shows a distorted square‐planar geometry around the Ni atom. The monomeric units are weakly associated into dimers viaa long Ni⃛S interaction [3.569 (1) Å]. These dimeric units are then linked by C—H⃛S intermolecular contacts to form a polymeric chain along the aaxis.
Details
- Language :
- English
- ISSN :
- 01082701 and 16005759
- Volume :
- 57
- Issue :
- 5
- Database :
- Supplemental Index
- Journal :
- Acta Crystallographica Section C: Crystal Structure Communications
- Publication Type :
- Periodical
- Accession number :
- ejs24562070
- Full Text :
- https://doi.org/10.1107/S0108270101001585