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A layered tin(II) phosphonate, [Sn(C6H5O3P)]n

Authors :
Lansky, David E.
Zavalij, Peter Y.
Oliver, Scott R. J.
Source :
Acta Crystallographica Section C: Crystal Structure Communications; September 2001, Vol. 57 Issue: 9 p1051-1052, 2p
Publication Year :
2001

Abstract

Poly­[tin(II)‐μ‐phenyl­phospho­nato], [Sn(C6H5O3P)]n, was synthesized solvothermally at 423 K and crystallized in the monoclinic system, space group Cc. The inorganic layers consist of alternating pyramidal Sn and tetrahedral P centers, joined by doubly bridging O atoms. The corner‐sharing SnO3and PO3C6H5polyhedra define a corrugated layer of six‐membered rings. The layers are connected along the unique baxis by interdigitated phenyl rings of the phenyl­phospho­nate groups.

Details

Language :
English
ISSN :
01082701 and 16005759
Volume :
57
Issue :
9
Database :
Supplemental Index
Journal :
Acta Crystallographica Section C: Crystal Structure Communications
Publication Type :
Periodical
Accession number :
ejs24591526
Full Text :
https://doi.org/10.1107/S0108270101010034