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Di­chloro­bis­(tri­methyl­ene­thio­urea‐κS)antimony(III) chloride

Authors :
Razak, Ibrahim Abdul
Usman, Anwar
Fun, Hoong‐Kun
Yamin, Bohari M.
Keat, Goh Wooi
Source :
Acta Crystallographica Section C: Crystal Structure Communications; February 2002, Vol. 58 Issue: 2 pm122-m123, 2p
Publication Year :
2002

Abstract

In the title compound, [SbCl2(C4H8N2S)2]Cl, the coordination around the Sb atom can be described as distorted pseudo‐octahedral. Both rings of the tri­methyl­ene­thio­urea ligands [alternatively 3,4,5,6‐tetrahydropyrimidine‐2(1H)‐thione] adopt an envel­ope conformation. The mol­ecules are connected into dimers in the abplane by two intermolecular hydrogen bonds. The dimers are arranged into infinite one‐dimensional chains along the aaxis as a result of the Cl−ions forming intermolecular hydrogen bonds with three NH groups.

Details

Language :
English
ISSN :
01082701 and 16005759
Volume :
58
Issue :
2
Database :
Supplemental Index
Journal :
Acta Crystallographica Section C: Crystal Structure Communications
Publication Type :
Periodical
Accession number :
ejs24592174
Full Text :
https://doi.org/10.1107/S0108270101020911