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Diacetatobis­(tri­methyl­ene­thio­urea)­zinc(II) monohydrate

Authors :
Razak, Ibrahim Abdul
Usman, Anwar
Fun, Hoong‐Kun
Yamin, Bohari M.
Keat, Goh Wooi
Source :
Acta Crystallographica Section C: Crystal Structure Communications; January 2002, Vol. 58 Issue: 1 pm31-m33, 3p
Publication Year :
2002

Abstract

In the title compound, [Zn(CH3COO)2(C4H8N2S)2]·H2O, the Zn atom is tetrahedrally coordinated in the ZnO2S2form. N—H⋯O and O—H⋯O intramolecular and intermolecular hydrogen bonds are formed by the four N atoms and the water mol­ecule. N—H⋯O intermolecular hydrogen bonds and C—H⋯S and C—H⋯O intermolecular interactions interconnect columns formed by the mol­ecules into layers. Adjacent layers are then linked by other N—H⋯O and O—H⋯O intermolecular hydrogen bonds to form a three‐dimensional framework throughout the structure. The orientations of the acetate planes are such that the Zn atom lies within them.

Details

Language :
English
ISSN :
01082701 and 16005759
Volume :
58
Issue :
1
Database :
Supplemental Index
Journal :
Acta Crystallographica Section C: Crystal Structure Communications
Publication Type :
Periodical
Accession number :
ejs24593205
Full Text :
https://doi.org/10.1107/S0108270101017577