ChemInform Abstract: Chiral P-Containing Palladacycle-Catalyzed Asymmetric Ring-Opening Reactions of Oxabicyclic Alkenes with Alkenyl Boronic Acids.

A wide range of oxabicyclic alkenes (I), (IV), and (VI) and alkenyl boronic acids (II) are suitable substrates for the palladacycle‐catalyzed asymmetric ring‐opening reaction to afford the corresponding products in good to very good yields and moderate to very good enantioselectivities.