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Mn(OAc)2/Schiff base as a new efficient catalyst system for the Henry reaction of nitroalkanes with aldehydes

Authors :
Zhou, Guang Peng
Hui, Yong Hai
Wan, Ning Ning
Liu, Qiu Ju
Xie, Zheng Feng
De Wang, Ji
Source :
Chinese Chemical Letters; June 2012, Vol. 23 Issue: 6 p690-694, 5p
Publication Year :
2012

Abstract

A series of novel Schiff bases bearing triazole structure were synthesized and characterized by IR and NMR. Mn(OAc)2/Schiff base efficiently catalyzed Henry reaction of nitroalkanes with aldehydes to produce the corresponding products of β-nitroalcohols, under mild conditions with high yields (up to 99%). A reaction mechanism is proposed based on the experimental results.

Details

Language :
English
ISSN :
10018417
Volume :
23
Issue :
6
Database :
Supplemental Index
Journal :
Chinese Chemical Letters
Publication Type :
Periodical
Accession number :
ejs27577935
Full Text :
https://doi.org/10.1016/j.cclet.2012.04.018