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Straightforward Approach toward SiO2Nanospheres and Their Superior Lithium Storage Performance

Authors :
Tu, Jiguo
Yuan, Yan
Zhan, Pan
Jiao, Handong
Wang, Xindong
Zhu, Hongmin
Jiao, Shuqiang
Source :
The Journal of Physical Chemistry - Part C; April 2014, Vol. 118 Issue: 14 p7357-7362, 6p
Publication Year :
2014

Abstract

SiO2nanospheres were prepared according to a straightforward approach and evaluated as an anode material for lithium-ion batteries. The morphologies display that the obtained amorphous SiO2powder has good uniform nanospheres with an average diameter of 400 nm. The SiO2anode shows an initial charge capacity of 622.1 mAh g–1, and it still remains at 876.7 mAh g–1even at a rate of 1 C over 500 cycles, showing a certain degree of increase. It can be considered that the superior performances are attributed to the partial generated Si, Li2O, and Li4SiO4matrixes acting as a shielding layer, hence improving the lithium storage performance. In short, the discussed results suggest that SiO2nanosphere is a promising anode material to improve the electrochemical performances for lithium-ion batteries.

Details

Language :
English
ISSN :
19327447 and 19327455
Volume :
118
Issue :
14
Database :
Supplemental Index
Journal :
The Journal of Physical Chemistry - Part C
Publication Type :
Periodical
Accession number :
ejs32407756
Full Text :
https://doi.org/10.1021/jp5011023