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An anionic silver(i) column containing a novel asymmetric double cage with embedded acetylenediide and unprecedented μ<SUB>5</SUB>-ligation of the nitrate ion

Authors :
Wang, Quan-Ming
Mak, Thomas C. W.
Source :
Dalton Transactions; January 2, 2003, Vol. 2003 Issue: 1 p25-27, 3p
Publication Year :
2003

Abstract

The new triple salt (PhCH&lt;SUB&gt;2&lt;/SUB&gt;NMe&lt;SUB&gt;3&lt;/SUB&gt;)&lt;SUB&gt;4&lt;/SUB&gt;[Ag&lt;SUB&gt;17&lt;/SUB&gt;(C&lt;SUB&gt;2&lt;/SUB&gt;)&lt;SUB&gt;2&lt;/SUB&gt;(CF&lt;SUB&gt;3&lt;/SUB&gt;CO&lt;SUB&gt;2&lt;/SUB&gt;)&lt;SUB&gt;16&lt;/SUB&gt;(NO&lt;SUB&gt;3&lt;/SUB&gt;)(H&lt;SUB&gt;2&lt;/SUB&gt;O)&lt;SUB&gt;4&lt;/SUB&gt;] (&lt;compoundref&gt;1&lt;/compoundref&gt;) features an asymmetric silver(i) double cage constructed from the edge-sharing of a triangulated dodecahedron and a monocapped square antiprism, and an anionic columnar structure is generated with an unprecedented μ&lt;SUB&gt;5&lt;/SUB&gt;-ligation mode of the nitrate ion.

Details

Language :
English
ISSN :
14779226 and 13645447
Volume :
2003
Issue :
1
Database :
Supplemental Index
Journal :
Dalton Transactions
Publication Type :
Periodical
Accession number :
ejs4063837

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