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Synthesis, Crystal Structure, and Magnetic Properties of the Highly Frustrated Orthorhombic Li4MgReO6
- Source :
- Inorganic Chemistry; 20240101, Issue: Preprints
- Publication Year :
- 2024
-
Abstract
- In an effort to understand the structure–property relationship in magnetically frustrated systems, an orthorhombic analog of the S= 1/2 Re-based oxide Li4MgReO6has been successfully synthesized and its physical properties were investigated. Li4MgReO6had been previously synthesized in a monoclinic system in an ordered NaCl structure type. That system was shown to exhibit spin glass behavior below ∼12 K. The crystal structure of the latter phase was determined using powder X-ray diffraction data. A structural model was refined in the orthorhombic Fdddspace group that resulted in cell dimensions of a= 5.84337 (7) Å, b= 8.33995 (9) Å, and c= 17.6237 (2) Å. The magnetic ions, Re6+(S= 1/2), consist of various arrangements of interconnected triangles and trigonal prisms that offer potential for geometric magnetic frustration. Temperature dependent magnetic susceptibility reveals an AFM transition below ∼2 K along with a ZFC/FC divergence suggestive of spin freezing. The Curie–Weiss fitting parameters to the paramagnetic regime result in θ = −124 (1) K, which is indicative of predominant AFM interactions. A frustration index of ∼62 is in accordance with a highly frustrated magnetic ground state. Zero field (ZF) μSRdata provides evidence for the onset of magnetic order below 4 K, along with the evidence for dynamical fluctuations up to 5 K. Moreover, longitudinal field (LF) μSRdata reveals a complete decoupling in applied field at 2 K, which is indicative of static order in most or all of the volume fraction at ∼2 K, with partial ordered volumes coexisting with dynamical fluctuations up to 5 K. Estimates of the relative strengths of various magnetic exchange pathways at the level of spin-dimer analysis for this novel system are calculated and are compared to those of the previously reported values for the monoclinic analog.
Details
- Language :
- English
- ISSN :
- 00201669 and 1520510X
- Issue :
- Preprints
- Database :
- Supplemental Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs43208925
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.7b01537