Crystal Chemistry and Photocatalytic Properties of RE4S4Te3(RE = Gd, Ho, Er, Tm): Experimental and Theoretical Investigations

Reported are the synthesis and structural characterization of a new series of ternary rare-earth mix-chalcogenides RE4S4Te3(RE = Gd, Ho, Er, Tm) that have been obtained from high-temperature solid state reactions. These compounds crystallize in Ho4S4Te2.68structure types with monoclinic C2/mand/or orthorhombic Immmspace groups. The space group variation within this series is due to the position disorder along the Te plane (Te to TeA and TeB). The structural relationship and change between these two space groups are analyzed. It is realized that these compounds are all photocatalytic active under simulated sunlight. The trend of their photocatalytic activities and photocurrent responses is well-explained by using theoretical calculation as well as dipole moment analysis.