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High-heat treatment enhanced catalytic activity of CuO/CeO2catalysts with low CuO content for CO oxidation
- Source :
- Catalysis Science & Technology; 2020, Vol. 10 Issue: 15 p5256-5266, 11p
- Publication Year :
- 2020
-
Abstract
- A series of CuO/CeO2catalysts with different CuO loadings (0.5, 1, 3, and 5 wt%) were prepared by an impregnation method, and tested for the total oxidation of CO. The samples were characterized by various structural and textural detection techniques including XRD, N2sorption, TEM-EDS, H2-TPR, XPS, and in situDRIFTS. Unexpectedly, the low CuO loading (0.5–3 wt%) samples calcined at high temperature (800 °C) exhibited better catalytic performance than those calcined at 500 °C, and the catalytic activity gap between the catalysts calcined at 500 °C and 800 °C shrunk with the increase of copper content. In contrast, when the loading amount of CuO reached a normal value (5 wt%), the CuO/CeO2catalyst with low temperature calcination (500 °C) obtained a slightly better activity than that calcined at 800 °C. The results showed that, for the catalysts with low CuO content (0.5–3 wt%), the higher temperature calcination (800 °C) can promote the formation of the coordinatively unsaturated copper atoms and increase the content of active Cu species, resulting in a higher activity than those calcined at 500 °C. But this effect was suppressed when the CuO content reached 5 wt%. The coordinatively unsaturated copper atoms, as well as Cu+, were confirmed to be the main active sites of the CuO/CeO2catalysts.
Details
- Language :
- English
- ISSN :
- 20444753 and 20444761
- Volume :
- 10
- Issue :
- 15
- Database :
- Supplemental Index
- Journal :
- Catalysis Science & Technology
- Publication Type :
- Periodical
- Accession number :
- ejs53959817
- Full Text :
- https://doi.org/10.1039/d0cy00757a