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Paraffin/Ti3C2TxMxene@Gelatin Aerogels Composite Phase-Change Materials with High Solar-Thermal Conversion Efficiency and Enhanced Thermal Conductivity for Thermal Energy Storage
- Source :
- Energy & Fuels; February 2021, Vol. 35 Issue: 3 p2805-2814, 10p
- Publication Year :
- 2021
-
Abstract
- The application of phase-change materials (PCMs) for solar energy utilization and thermal energy storage is limited by their low thermal conductivity, undesirable solar-thermal conversion efficiency, and poor shape stability. Here, the novel paraffin/Ti3C2Tx@gelatin (PA/T@G) composite PCMs were successfully obtained by encapsulating paraffin (PA) into gelatin aerogels modified by Ti3C2Txnanosheets. Three-dimensional (3D) porous gelatin aerogel acted as a favorable supporting material for PA with large enthalpy, while the Ti3C2Txnanosheets contributed to enhancing the thermal conductivity and converting solar energy into thermal energy by trapping photons and heating molecules. The results exhibited that the composite PCMs had high load rates (96.3–97.7%) and large melting enthalpies (184.7–199.9 J/g). The thermal conductivity of PA/T-30@G was 0.919 W/(m·K), which reached up to 3.48 times that of PA, and the solar-thermal conversion efficiency of the composite PCMs was greatly improved via the introduction of Ti3C2Txnanosheets. Notably, the composite PCMs with good shape and thermal stability is a promising material for solar-thermal energy storage applications.
Details
- Language :
- English
- ISSN :
- 08870624 and 15205029
- Volume :
- 35
- Issue :
- 3
- Database :
- Supplemental Index
- Journal :
- Energy & Fuels
- Publication Type :
- Periodical
- Accession number :
- ejs55631443
- Full Text :
- https://doi.org/10.1021/acs.energyfuels.0c04275