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A Method for the Highly Selective, Colorimetric and Ratiometric Detection of Hg2+in a 100% Aqueous Solution

Authors :
Liu, Jingkai
Xu, Zhenghe
Xu, Lirong
Bian, Zhen
Sang, Guoqing
Zhu, Baocun
Source :
Analytical Sciences; March 2016, Vol. 32 Issue: 3 p361-365, 5p
Publication Year :
2016

Abstract

Mercury (Hg) and its derivatives pose a serious threat to the environment and human health. Thus, the development of methods for the selective and sensitive determination of Hg2+is very important to understand its distribution, and to implement more detailed toxicological studies. Herein, we developed a new method for the detection of Hg2+based on the tricyanoethylene derivative and mercaptoethanol. This method could selectively detect Hg2+in a 100% aqueous solution by the naked-eye within the range of 1 – 60 μM. Importantly, this method also could detect Hg2+quantitatively by ratiometic absorption spectroscopy in the range of 0.1 – 6 μM with a detection limit of 55 nM. We anticipate that this proposed method will be used widely to monitor Hg2+in the environment.

Details

Language :
English
ISSN :
09106340 and 13482246
Volume :
32
Issue :
3
Database :
Supplemental Index
Journal :
Analytical Sciences
Publication Type :
Periodical
Accession number :
ejs60224320
Full Text :
https://doi.org/10.2116/analsci.32.361