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Synthesis of Enamines, Aldehydes, and Nitriles from CO2: Scope of the One-Pot Strategy via Formamides
- Source :
- The Journal of Organic Chemistry; November 2023, Vol. 88 Issue: 21 p15444-15451, 8p
- Publication Year :
- 2023
-
Abstract
- Tetrabutylammonium acetate (TBAA) and Cu(OAc)2worked as a binary catalytic system for the solvent-free N-formylation of amines with CO2and PhSiH3. This catalysis making C–H and C–N bonds with CO2was coupled with the C–C bond-forming reactions to achieve the one-pot synthesis of enamines, aldehydes, and nitriles. The X-ray crystal structure of a Cu(OAc)2–TBAA complex was also revealed.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 88
- Issue :
- 21
- Database :
- Supplemental Index
- Journal :
- The Journal of Organic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs60732127
- Full Text :
- https://doi.org/10.1021/acs.joc.2c01666