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CARBON-13 NMR STUDY OF AN INTERMEDIATE COMPLEX IN HYDROESTERIFICATION OF OLEFINS
- Source :
- Chemistry Letters; February 1977, Vol. 6 Issue: 2 p115-118, 4p
- Publication Year :
- 1977
-
Abstract
- Reaction of a new hydroesterification catalyst H2Co3Py5(CO)9with 2-vinylpyridine yielded an alkylcobalt complex (Remark: Graphics omitted.), which is considered to be an intermediate complex in the hydroesterification of 2-vinylpyridine. The 13C-NMR parameters of the α- and β-methylene groups were δ=60.0 ppm (JC-H=147 Hz) and 37.4 ppm (132 Hz), respectively.
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 6
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs64675803
- Full Text :
- https://doi.org/10.1246/cl.1977.115