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SYNTHESIS AND ABSOLUTE CONFIGURATION OF (−)-D3-TRITWISTANE, (−)-(1S,3S,6S,7S,10S,12S)PENTACYCLO[8.4.0.02,7.03,12.06,11]TETRADECANE
- Source :
- Chemistry Letters; December 1980, Vol. 9 Issue: 12 p1571-1572, 2p
- Publication Year :
- 1980
-
Abstract
- Diazomethane ring expansion of 12-acetoxy-C2-bismethanotwistan-8-one (11) followed by the Wolff–Kishner reduction and the Jones oxidation gave C2-methanoditwistan-4-one (14) whose incubation with Rhodotorula rubraafforded the (−)-enantiomer 16, which was converted into (−)-(1S,3S,6S,7S,10S,12S)-D3,-tritwistane (7).
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 9
- Issue :
- 12
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs64676601
- Full Text :
- https://doi.org/10.1246/cl.1980.1571