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Synthesis of hydroxy acids via the light-driven carboxylation of epoxides with CO2
- Source :
- Chemistry Letters; May 2024, Vol. 53 Issue: 5
- Publication Year :
- 2024
-
Abstract
- Light-driven ring-opening carboxylation of epoxides with CO2provided β-hydroxy acids via sequential single electron transfer (SET), followed by reaction with CO2. This reaction condition was applicable to aryl epoxides and oxetanes with (hetero)polycyclic aromatics to give the corresponding β- and γ-hydroxy acids, respectively, with high chemoselectivity.Graphical Abstractβ-Hydroxy acids were successfully synthesized by the light-driven ring-opening carboxylation of epoxides with CO2. Aryl epoxides and oxetanes with (hetero)polycyclic aromatics were converted into the corresponding β- and γ-hydroxy acids, respectively, with high chemoselectivity.
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 53
- Issue :
- 5
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs66502805
- Full Text :
- https://doi.org/10.1093/chemle/upae086