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Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid
- Source :
- Journal of Fuel Chemistry and Technology; June 2024, Vol. 52 Issue: 6 p883-892, 10p
- Publication Year :
- 2024
-
Abstract
- Formic acid (FA) is a sustainable liquid organic hydrogen carrier and the catalyst for hydrogen production from FA has received significant attention. However, the development of efficient non-noble metal catalysts still remains challenges. In this work, we provide a technologically rather simple and environmental-friendly strategy to synthesize Co2P catalyst for dehydrogenation of FA by pyrolyzing soybean powder and cobalt salt. The K-containing solid bases in catalyst could act as Lewis acid sites for the HCOO−intermediate adsorption while the self-doped N could act as Lewis base sites to enhance the H+adsorption. The P contained in soybean could combine with Co to form Co2P for H−C bond cleavage of HCOO−. At a Co(NO3)2·6H2O/soybean mass ratio of 1:15, the as prepared Co2P catalyst demonstrated a gas production rate of 237.47 mL/(g·h) and a good stability. This study provides a novel strategy to develop non-noble metal heterogeneous catalysts for FA dehydrogenation.
Details
- Language :
- English
- ISSN :
- 18725813
- Volume :
- 52
- Issue :
- 6
- Database :
- Supplemental Index
- Journal :
- Journal of Fuel Chemistry and Technology
- Publication Type :
- Periodical
- Accession number :
- ejs66510314
- Full Text :
- https://doi.org/10.1016/S1872-5813(23)60410-4