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Plasticity in single-crystalline Mg3Bi2thermoelectric material
- Source :
- Nature; July 2024, Vol. 631 Issue: 8022 p777-782, 6p
- Publication Year :
- 2024
-
Abstract
- Most of the state-of-the-art thermoelectric materials are inorganic semiconductors. Owing to the directional covalent bonding, they usually show limited plasticity at room temperature1,2, for example, with a tensile strain of less than five per cent. Here we discover that single-crystalline Mg3Bi2shows a room-temperature tensile strain of up to 100 per cent when the tension is applied along the (0001) plane (that is, the abplane). Such a value is at least one order of magnitude higher than that of traditional thermoelectric materials and outperforms many metals that crystallize in a similar structure. Experimentally, slip bands and dislocations are identified in the deformed Mg3Bi2, indicating the gliding of dislocations as the microscopic mechanism of plastic deformation. Analysis of chemical bonding reveals multiple planes with low slipping barrier energy, suggesting the existence of several slip systems in Mg3Bi2. In addition, continuous dynamic bonding during the slipping process prevents the cleavage of the atomic plane, thus sustaining a large plastic deformation. Importantly, the tellurium-doped single-crystalline Mg3Bi2shows a power factor of about 55 microwatts per centimetre per kelvin squared and a figure of merit of about 0.65 at room temperature along the abplane, which outperforms the existing ductile thermoelectric materials3,4.
Details
- Language :
- English
- ISSN :
- 00280836 and 14764687
- Volume :
- 631
- Issue :
- 8022
- Database :
- Supplemental Index
- Journal :
- Nature
- Publication Type :
- Periodical
- Accession number :
- ejs66888063
- Full Text :
- https://doi.org/10.1038/s41586-024-07621-8