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MALDI TOF Mass Study on Oligomerization of Pd(OAc)<INF>2</INF>(L)<INF>2</INF> (L = Pyridine Derivatives):  Relevance to Pd Black Formation in Pd-Catalyzed Air Oxidation of Alcohols

Authors :
Komano, T.
Iwasawa, T.
Tokunaga, M.
Obora, Y.
Tsuji, Y.
Source :
Organic Letters; October 2005, Vol. 7 Issue: 21 p4677-4679, 3p
Publication Year :
2005

Abstract

&lt;UFIGR ID=&quot;ol051845on00001&quot;&gt;Oligomerization of Pd(OAc)&lt;INF&gt;2&lt;/INF&gt;(L)&lt;INF&gt;2&lt;/INF&gt; (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis.

Details

Language :
English
ISSN :
15237060 and 15237052
Volume :
7
Issue :
21
Database :
Supplemental Index
Journal :
Organic Letters
Publication Type :
Periodical
Accession number :
ejs7836979