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Chiral 1,2-ethanediyl-spaced quaterpyridines give a library of cyclic and double helicates with copper(I)
- Source :
- Chemical Communications; January 21, 1999, Vol. 1999 Issue: 2 p195-196, 2p
- Publication Year :
- 1999
-
Abstract
- A new enantiomeric pair of ligands in which a 2,2′:6′,2″:6″,2″′-quaterpyridine has been split into two 2,2′-bipyridine binding domains by a CH2CH2 spacer has been prepared: reaction with Ag(I) gives dinuclear double helicates whereas Cu(I) gives a library of {CuL}nn+ complexes (n = 2,3,4,5) of which the compounds with n = 2,3 have been structurally characterised as double helicates and cyclohelicates respectively.
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Volume :
- 1999
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Chemical Communications
- Publication Type :
- Periodical
- Accession number :
- ejs7992711
- Full Text :
- https://doi.org/10.1039/a809230c