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A predicative model for certain directed metalations, IV; The dynamic behavior of the organolithio intermediates formed by metalation of p-dimethoxybenzene (p-DMB)

Authors :
Slocum, D.W.
Hayes, G.
Kline, N.
Source :
Tetrahedron Letters; November 1995, Vol. 36 Issue: 45 p8175-8178, 4p
Publication Year :
1995

Abstract

Significant disproportionation between the mono- and 2,5-bis-metalaled intermediates resulting from metalation of p-DMB has been observed. The best procedure for the generation of each of these intermediates involves use of an “incremental” amount of TMEDA.1

Details

Language :
English
ISSN :
00404039
Volume :
36
Issue :
45
Database :
Supplemental Index
Journal :
Tetrahedron Letters
Publication Type :
Periodical
Accession number :
ejs8309269
Full Text :
https://doi.org/10.1016/0040-4039(95)01765-A