Development of vacuum‐ultraviolet circular dichroism measurement system using a polarizing undulator

We have developed an improved circular dichroism (CD) and linear dichroism (LD) simultaneous measurement system for the vacuum ultraviolet (VUV) region by polarization modulation techniques using a four‐period Onuki‐type crossed undulator as a polarized light source. The system has been constructed at the VUV beamline BL‐5 in the electron storage ring TERAS, at AIST. Our improvements, in particular the adoption of an optical chopper as the detection method of incident light, have resulted in a flat baseline and a consequent simplification of the Mueller matrix calculation for our optical system. Based on the Mueller matrix calculation, we have successfully measured real VUV‐CD and LD spectra of leucine films for wavelengths down to 160 nm with absolute optical constants. The obtained spectra show good consistency with spectra measured by conventional methods. © 2006 Wiley‐Liss, Inc. Chirality