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Direct Synthesis of Deep Cavity p-Phenylcalix[4]arene in Poly(Ethylene Glycol), and its Self-Association in the Solid State

Authors :
Makha, Mohamed
Raston, Colin L.
Sobolev, Alexandre N.
Source :
Australian Journal of Chemistry; 2006, Vol. 59 Issue: 4 p260-262, 3p
Publication Year :
2006

Abstract

p-Phenylcalix[4]arene is formed directly from p-phenylphenol in 66% yield (50% isolated yield) using poly(ethylene glycol) as the reaction medium, with crystallization of the pure cavitand from toluene mediated by p-carborane. The solid-state structure comprises interlocking columnar arrays.

Details

Language :
English
ISSN :
00049425 and 14450038
Volume :
59
Issue :
4
Database :
Supplemental Index
Journal :
Australian Journal of Chemistry
Publication Type :
Periodical
Accession number :
ejs8859345
Full Text :
https://doi.org/10.1071/CH06080