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Ionic Liquid Metal-Conjugates: Formation of an Imidazolium Dirhodium(II) Carboxylate
- Source :
- Organometallics; May 2006, Vol. 25 Issue: 10 p2693-2695, 3p
- Publication Year :
- 2006
-
Abstract
- A transition metal complex covalently bound to an organic salt offers a unique opportunity to explore issues of catalysis in an ionic liquid medium. Ligand exchange of acetate with an imidazolium functionality tethered to a carboxylic acid afforded the desired metal-conjugate. The modified dirhodium(II) dimer was found to be an effective catalyst in the intermolecular cyclopropanation reaction of styrene using ethyl diazoacetate.
Details
- Language :
- English
- ISSN :
- 02767333 and 15206041
- Volume :
- 25
- Issue :
- 10
- Database :
- Supplemental Index
- Journal :
- Organometallics
- Publication Type :
- Periodical
- Accession number :
- ejs9004408