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NMR studies of ammoniated NaA"2C"6"0 superconductors
- Source :
- Synthetic Metals; June 1999, Vol. 103 Issue: 1-3 p2458-2461, 4p
- Publication Year :
- 1999
-
Abstract
- ^1^3C-NMR studies of new class of C"6"0 superconductors, (NH"3)"xNaA"2C"6"0 with A=K or Rb, are reported. The results are compared with the other classes of A"3C"6"0 superconductors. In fee A"3C"6"0, an examination of the modified Korringa relation, T"1TK^2~@bS showed existence of weak but substantial antiferromagnetic spin fluctuation in A"3C"6"0; @b=0.40~0.58 with an error of +/-20 %. Stoner enhancement factor was also determined as 1~1.5. The temperature dependent T"1TK^2, which becomes significant at high temperature (>~100 K), is suggested to be explained by an enhancement effect related to short mean free path in the present materials. In (NH"3)"xNaA"2C"6"0, a gap-like behavior in temperature dependence of ^1^3C-spin lattice relaxation rate was observed. C"6"0 and NH"3 molecular dynamics are also discussed.
Details
- Language :
- English
- ISSN :
- 03796779
- Volume :
- 103
- Issue :
- 1-3
- Database :
- Supplemental Index
- Journal :
- Synthetic Metals
- Publication Type :
- Periodical
- Accession number :
- ejs9201777
- Full Text :
- https://doi.org/10.1016/S0379-6779(98)00343-9