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NMR studies of ammoniated NaA"2C"6"0 superconductors

Authors :
Maniwa, Y.
Muroga, N.
Tou, H.
Kikuchi, K.
Suzuki, S.
Achiba, Y.
Kosaka, M.
Tanigaki, K.
Iwasa, Y.
Shimoda, H.
Mitani, T.
Source :
Synthetic Metals; June 1999, Vol. 103 Issue: 1-3 p2458-2461, 4p
Publication Year :
1999

Abstract

^1^3C-NMR studies of new class of C"6"0 superconductors, (NH"3)"xNaA"2C"6"0 with A=K or Rb, are reported. The results are compared with the other classes of A"3C"6"0 superconductors. In fee A"3C"6"0, an examination of the modified Korringa relation, T"1TK^2~@bS showed existence of weak but substantial antiferromagnetic spin fluctuation in A"3C"6"0; @b=0.40~0.58 with an error of +/-20 %. Stoner enhancement factor was also determined as 1~1.5. The temperature dependent T"1TK^2, which becomes significant at high temperature (>~100 K), is suggested to be explained by an enhancement effect related to short mean free path in the present materials. In (NH"3)"xNaA"2C"6"0, a gap-like behavior in temperature dependence of ^1^3C-spin lattice relaxation rate was observed. C"6"0 and NH"3 molecular dynamics are also discussed.

Details

Language :
English
ISSN :
03796779
Volume :
103
Issue :
1-3
Database :
Supplemental Index
Journal :
Synthetic Metals
Publication Type :
Periodical
Accession number :
ejs9201777
Full Text :
https://doi.org/10.1016/S0379-6779(98)00343-9