Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration

Authors :: Ruscoe, Rebecca E.
Callingham, Michael
Baker, Joshua A.
Korkis, Stamatis E
Lam, Hon Wai
Publication Year :: 2018
Publisher :: Royal Society of Chemistry, 2018.
Abstract: A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(I) migration.

Subjects :: Materials Chemistry
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films

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