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Synthesis of Fluorine-Containing 3,3-Disubstituted Oxetanes and Alkylidene Oxetanes
- Source :
- European Journal of Organic Chemistry, European Journal of Organic Chemistry, Wiley-VCH Verlag, 2015, 2015 (14), pp.3121-3128. ⟨10.1002/ejoc.201500172⟩, European Journal of Organic Chemistry, 2015, 2015 (14), pp.3121-3128. ⟨10.1002/ejoc.201500172⟩
- Publication Year :
- 2015
- Publisher :
- HAL CCSD, 2015.
-
Abstract
- International audience; Access to fluoroalkylidene-oxetanes and-azetidines was realized from 3-oxetanone, 3-azetidinone, and fluorosulfones through the Julia-Kocienski reaction. This approach allows the preparation of new precursors of fluorinated four-membered rings that contain a nucleic base, an ester or aryl sulfone function, and a pyrrolidine ring. Benzothiazolyl-sulfonemediated aza-Michael addition reaction of nitrogen nucleophiles enables access to 3,3-disubstituted oxetanes.
- Subjects :
- [CHIM.ORGA]Chemical Sciences/Organic chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X and 10990690
- Database :
- OpenAIRE
- Journal :
- European Journal of Organic Chemistry, European Journal of Organic Chemistry, Wiley-VCH Verlag, 2015, 2015 (14), pp.3121-3128. ⟨10.1002/ejoc.201500172⟩, European Journal of Organic Chemistry, 2015, 2015 (14), pp.3121-3128. ⟨10.1002/ejoc.201500172⟩
- Accession number :
- edsair.dedup.wf.001..77c678f3217713433f85c6db7adfe81a
- Full Text :
- https://doi.org/10.1002/ejoc.201500172⟩