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Cyclization of gamma-delta-Epoxy-alfa-cyanosulfones. A Simple, DiastereoselectiveRoute to Cyclopropane Carboxylic Acids

Authors :
BENEDETTI, FABIO
BERTI, FEDERICO
RISALITI, AMERIGO
Benedetti, Fabio
Berti, Federico
Risaliti, Amerigo
Publication Year :
1993

Abstract

Cyclisation of alfa-cyano-alfa-sulfonyl-gamma,delta-epoxy carbanions proceeds with high yields and complete diastereoselectivity to yield cyclopropanolactones, useful intermediates in the synthesis of cis-substituted cyclopropane carboxylic acids.

Details

Language :
English
Database :
OpenAIRE
Accession number :
edsair.dedup.wf.001..d25ec769d2c8efb96bf051d710bc9d91