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Bis[μ-4-(dimethylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(dimethylamino)benzoato-κ2O,O′](nicotinamide-κN1)cadmium(II)}
- Source :
- Acta Crystallographica Section E, Vol 66, Iss 7, Pp m782-m783 (2010)
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- In the centrosymmetric dimeric CdII title compound, [Cd2(C9H10NO2)4(C6H6N2O)2(H2O)2], each seven-coordinated CdII atom is chelated by the carboxylate groups of the two 4-(dimethylamino)benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. Weak C—H...π interactions are also observed.
- Subjects :
- lcsh:Chemistry
lcsh:QD1-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- 7
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E
- Accession number :
- edsair.doajarticles..5bb96abcf17e993fa1f7f88779c3364a