Back to Search Start Over

Bis[μ-4-(dimethylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(dimethylamino)benzoato-κ2O,O′](nicotinamide-κN1)cadmium(II)}

Authors :
Tuncer Hökelek
Yasemin Süzen
Barış Tercan
Özgür Aybirdi
Hacali Necefoğlu
Source :
Acta Crystallographica Section E, Vol 66, Iss 7, Pp m782-m783 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the centrosymmetric dimeric CdII title compound, [Cd2(C9H10NO2)4(C6H6N2O)2(H2O)2], each seven-coordinated CdII atom is chelated by the carboxylate groups of the two 4-(dimethylamino)benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. Weak C—H...π interactions are also observed.

Subjects

Subjects :
lcsh:Chemistry
lcsh:QD1-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
7
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E
Accession number :
edsair.doajarticles..5bb96abcf17e993fa1f7f88779c3364a