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Rational Design of a Tripodal Ligand for U(IV): Synthesis and Characterization of a U–Cl Species and Insights into Its Reactivity

Authors :
Kong-qiu Hu
Kang Liu
Li-Yong Yuan
Xiang-He Kong
Lei Mei
Wei-Qun Shi
Qun-Yan Wu
Jipan Yu
Zhifang Chai
Xue-Bing Tao
Source :
Organometallics. 39:4069-4077
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

The rational design and synthesis of the Trapen ligand (1, tris(2-aminobenzyl)amine) with a tripodal scaffold is reported. Treatment of Trapen with n-BuLi and TMSCl results in the formation of the ...

Details

ISSN :
15206041 and 02767333
Volume :
39
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........00c73eccc15e2b623b55a4dbfc747a45
Full Text :
https://doi.org/10.1021/acs.organomet.0c00638