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Synthesis, crystal structure and magnetic properties of one-dimensional cyano-bridged bimetallic complex of [Mn(Me2-bipy)2]3[W(CN)8]2·9H2O
- Source :
- Inorganic Chemistry Communications. 12:1179-1181
- Publication Year :
- 2009
- Publisher :
- Elsevier BV, 2009.
-
Abstract
- An octacyanotungstate(V)-manganese(II) bimetallic assembly [Mn(Me2-bipy)2]3[W(CN)8]2·9H2O (1) (Me2-bipy = 4,4′-dimethyl-2,2′-bipyridine) was synthesized in methanol and characterized by X-ray crystallography. X-ray analysis shows that complex 1 is a neutral, one-dimensional (1D) infinite chain polymer. Magnetic data analysis demonstrates a long-range magnetic interaction and two different antiferromagnetic coupling constants obtained by fitting between Mn and W ions in 1.
Details
- ISSN :
- 13877003
- Volume :
- 12
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........01240236b924acfc70bc1d3867405af2