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From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes

Authors :
Daisuke Ohira
Shuntaro Mataka
Masashi Tashiro
Yuanqiang Li
Thies Thiemann
Carolin Thiemann
Source :
Journal of Chemical Research. 2009:702-704
Publication Year :
2009
Publisher :
SAGE Publications, 2009.

Abstract

Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr3.

Details

ISSN :
20476507 and 17475198
Volume :
2009
Database :
OpenAIRE
Journal :
Journal of Chemical Research
Accession number :
edsair.doi...........02fd017d33a6f3e1a2f0239f0ec171e4