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Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3 with HC⋮CCMe3
- Source :
- Organometallics. 19:3757-3761
- Publication Year :
- 2000
- Publisher :
- American Chemical Society (ACS), 2000.
-
Abstract
- Treatment of OsCl2(PPh3)3 with HC⋮CCMe3produced a mixture of OsCl3(⋮CCH2CMe3)(PPh3)2 and OsCl(CCHCMe3)(C(C⋮CCMe3)CHCMe3)(PPh3)2. The structures of the new complexes have been confirmed by X-ray diffraction studies.
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 19
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........040ef8183e125faf6bd76734b760b9c0
- Full Text :
- https://doi.org/10.1021/om000306e