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ChemInform Abstract: Kinetics and Mechanism of Carbothermic Reduction of MoO3 to Mo2C

Authors :
Satyajeet Chaudhury
Subroto Mukerjee
V. Venugopal
V.N. Vaidya
Source :
ChemInform. 29
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

The kinetics of carbothermic reduction of molybdenum oxide with homogeneously mixed carbon black was studied under non-isothermal heating conditions using a thermobalance. The evolved gases (CO and CO 2 ) were analysed by a gas chromatograph. A mechanism is proposed to explain the stepwise conversion of oxide to carbide. A model representing stepwise conversion of the above reduction has been developed and the probable rate controlling steps, for different reactions, have been identified.

Details

ISSN :
15222667 and 09317597
Volume :
29
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........0978857aa1084aeb975e0f3b5ccef759