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Simultaneous underpotential deposition of lead and thallium on polycrystalline silver-III
- Source :
- Journal of Applied Electrochemistry. 24:981-988
- Publication Year :
- 1994
- Publisher :
- Springer Science and Business Media LLC, 1994.
-
Abstract
- Simultaneous underpotential deposition of lead and thallium from a tartrate medium on a polycrystalline silver electrode is reported. Results of cyclic voltammetric investigations of the effects of concentration and sweep rate on the codeposition behaviour are discussed. Further investigations of the codeposition behaviour through voltammetric experiments using programmed potential inputs are described and discussed in terms of formation of a two-dimensional alloy. Finally, the validity of the existing models of electrochemical phase formation has been investigated under the codeposition conditions.
- Subjects :
- Materials science
General Chemical Engineering
Alloy
Inorganic chemistry
chemistry.chemical_element
engineering.material
Tartrate
Underpotential deposition
Electrochemistry
Phase formation
Silver electrode
chemistry.chemical_compound
chemistry
Materials Chemistry
engineering
Thallium
Crystallite
Subjects
Details
- ISSN :
- 15728838 and 0021891X
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- Journal of Applied Electrochemistry
- Accession number :
- edsair.doi...........09f0b00a9a92c437095ed756eb42809b