ChemInform Abstract: Photochemistry of Large-Ring 2-Phenylcycloalkanones in Various Environments. Intramolecular Para Coupling Products of Acyl Benzyl Biradicals

Authors :: Nicholas J. Turro
Xuegong Lei
Nianhe Han
Source :: ChemInform. 22
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: The dominant products from the photolysis of large α-phenylcycloalkanones are the cyclophanes formed by the intramolecular para coupling of the acyl benzyl biradical intermediate. This tendency to form cyclophanes is preserved under a variety of environmental conditions (organic solvents, micelles, and zeolites)

Subjects :: Coupling (electronics)
Chemistry
Intramolecular force
Photodissociation
General Medicine
Ring (chemistry)
Photochemistry
Micelle

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