Picosecond Forward Electron Transfer and Nanosecond Back Electron Transfer in an Azacrown-Substituted [(bpy)Re(CO)3(L)]+ Complex: Direct Observation by Time-Resolved UV−Visible Absorption Spectroscopy

Authors :: John N. Moore
Jared D. Lewis
Robin N. Perutz
Laura Bussotti
Paolo Foggi
Source :: The Journal of Physical Chemistry A. 106:12202-12208
Publication Year :: 2002
Publisher :: American Chemical Society (ACS), 2002.
Abstract: Intramolecular electron transfer in the excited state of a [(bpy)ReI(CO)3(L)]+ complex (bpy = 2,2‘-bipyridine), in which L contains a pendant azacrown ether that acts as an electron donor (L = N-[4...

Subjects :: chemistry.chemical_compound
Electron transfer
chemistry
Picosecond
Intramolecular force
Excited state
Electron donor
Ether
Physical and Theoretical Chemistry
Nanosecond
Spectroscopy
Photochemistry

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