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Enhanced performance of extruded–spheronized carbide slag pellets for high temperature CO 2 capture
- Source :
- Chemical Engineering Journal. 285:293-303
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- The pelletization of carbide slag is necessary for its practical application in the calcium looping process (CLP). In this work, CaO-based pellets were prepared from carbide slag waste via a novel method of extrusion–spheronization. However, this granulation method results in a loss of specific surface area and, consequently, inferior CO2 sorption performance of the carbide slag pellets. Two types of biomass-based pore-forming materials (microcrystalline cellulose and rice husk) were used for the first time to modify the pore structures of the pellets, and thus enhance their CO2 sorption performance. The addition of 20 wt.% microcrystalline cellulose is effective in improving the CO2 sorption of carbide slag pellets, displaying a high conversion of 52.64% in the 25th cycle. However, the additions of 10 and 20 wt.% rice husk both result in inferior cyclic CO2 capture performance owing to the aggravated sorbent sintering caused by the new eutectics, which are from the combination of aluminosilicate with the potassium contained in the rice husk. The pellets doped with 20 wt.% pre-washed rice husk (most potassium removed) display the highest 25th carbonation conversion of 51.02%, which is almost 1.46 times that of the pellets doped with raw rice husk. The addition of pore-forming materials weakens the pellets’ mechanical strength, and 5–10 wt.% addition of cement could enhance the mechanical strength and maintain the relatively good CO2 sorption performance of the pellets.
- Subjects :
- Materials science
Waste management
General Chemical Engineering
Metallurgy
Pellets
Slag
Sorption
02 engineering and technology
General Chemistry
021001 nanoscience & nanotechnology
Husk
Industrial and Manufacturing Engineering
Carbide
Microcrystalline cellulose
chemistry.chemical_compound
Granulation
020401 chemical engineering
chemistry
visual_art
visual_art.visual_art_medium
Environmental Chemistry
0204 chemical engineering
0210 nano-technology
Calcium looping
Subjects
Details
- ISSN :
- 13858947
- Volume :
- 285
- Database :
- OpenAIRE
- Journal :
- Chemical Engineering Journal
- Accession number :
- edsair.doi...........0bf023377cdd8060cc41ba3a52591bf8