Structure of two encapsulated cobalt(III) complexes containing cyclo-triphosphate

Authors :: F. Ferranti
Alessia Bacchi
Giancarlo Pelizzi
Source :: Acta Crystallographica Section C Crystal Structure Communications. 49:1885-1892
Publication Year :: 1993
Publisher :: International Union of Crystallography (IUCr), 1993.
Abstract: The conformational and packing properties of two encapsulated cobalt(III) complexes containing cyclo-triphosphate have been investigated. Compound (I), (1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]icosane)cobalt(III) cyclo-triphosphate-water (2/7) has the trivial name cobalt(III) sepulchrate cyclo-triphosphate-water (2/7) and chemical formula [Co(sep)](P 3 O 9 ).3.5H 2 O. The cation shows an lel 3 geometry very similar to those found in other sepulchrate complexes

Subjects :: Bicyclic molecule
Chemistry
Stereochemistry
Metaphosphate
chemistry.chemical_element
General Medicine
Crystal structure
Medicinal chemistry
General Biochemistry, Genetics and Molecular Biology
chemistry.chemical_compound
Icosane
Molecule
Amine gas treating
Hydrate
Cobalt

ISSN :: 01082701
Volume :: 49
Database :: OpenAIRE
Journal :: Acta Crystallographica Section C Crystal Structure Communications
Accession number :: edsair.doi...........0cc3a9ba21cf055077424d76c1a8e3be
Full Text :: https://doi.org/10.1107/s0108270193004263

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