Back to Search
Start Over
Acid-assisted hydrogenation of CO2 to methanol using Ru(<scp>ii</scp>) and Rh(<scp>iii</scp>) RAPTA-type catalysts under mild conditions
- Source :
- Chemical Communications. 57:8941-8944
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- A highly efficient homogeneous catalyst system for production of CH3OH from CO2 using single molecular defined ruthenium and rhodium RAPTA-type catalysts [Ru(η6-p-cymene)X2(PTA)] (X = I(1), Cl(2); PTA = 1,3,5-triaza-7-phosphaadamantane) and rhodium catalysts [Rh(η5-C5Me5)X2(PTA/PTA-BH3)] (X = Cl(3), H(4) and PTA-BH3, H(5)) developed in acidic media under mild conditions. A TON of 4752 is achieved using a [Ru(η6-p-cymene)I2(PTA)] catalyst which represents the first example of CO2 hydrogenation to CH3OH using single molecular defined Ru and Rh RAPTA-type catalysts.
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi...........0f78cf4fce3e04030c7c4a0cdf33835c