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ChemInform Abstract: Organocatalytic Asymmetric Allylic Alkylation of Oxindoles with Morita-Baylis-Hillman Carbonates

Authors :
Ying-Chun Chen
Jing Peng
Hai-Lei Cui
Kun Jiang
Source :
ChemInform. 40
Publication Year :
2009
Publisher :
Wiley, 2009.

Abstract

The organic Lewis base-catalysed asymmetric allylic alkylation of 3-substituted oxindoles with Morita–Baylis–Hillman carbonates is reported, affording multifunctional oxindoles with adjacent quaternary and tertiary chiral centres (dr up to 92 : 8, 86–97% ee).

Details

ISSN :
15222667 and 09317597
Volume :
40
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........129469a8efd9bc155007e667f9291076