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Suppression of Electroreductive Dimerization of Benzaldehyde by Addition of α-Cyclodextrin
- Source :
- Bulletin of the Chemical Society of Japan. 56:1305-1307
- Publication Year :
- 1983
- Publisher :
- The Chemical Society of Japan, 1983.
-
Abstract
- The effect of α-cyclodextrin (α-CD) on the electroreduction of benzaldehyde was investigated. The reduction in aqueous system produces benzyl alcohol and 1,2-diphenyl-1,2-ethanediol (hydrobenzoin, dimerization product). The addition of α-CD caused the decrease in the yield of hydrobenzoin. This suppression effect was observed both in the controlled potential and controlled current electrolyses. This is accounted for by the retardation of the dimerization rate between the neutral radicals, since inclusion of substrate provides severe steric hindrance around the reaction site. The addition had only a small influence on the stereochemistry of hydrobenzoin formed by the dimerization.
Details
- ISSN :
- 13480634 and 00092673
- Volume :
- 56
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Chemical Society of Japan
- Accession number :
- edsair.doi...........1311e49ddb62362d48b263063749669a
- Full Text :
- https://doi.org/10.1246/bcsj.56.1305