The influence of arrangement of substituents in isomeric chlorobenzenes on their adsorption on graphite

Henry's constants and the heats of adsorption of benzene chloro derivatives on graphitized thermal carbon black were calculated by the semiempirical molecular statistical theory of adsorption. The best agreement between the experimental and calculated data was achieved by introducing corrections for the presence of other chlorine atoms in theortho-positions into the calculation of the atom-atomic potential of the intermolecular interaction of the chlorine atom with the carbon atom of graphite.