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Sulfonyl chloride as a disposable electron withdrawing substituent in halex fluorinations

Authors :
Hiroshi Suzuki
Hiroyuki Kageyama
Yoshikazu Kimura
Source :
Journal of Fluorine Chemistry. 101:85-89
Publication Year :
2000
Publisher :
Elsevier BV, 2000.

Abstract

Syntheses of 1,3-difluorobenzene and 2,6-difluorotoluene are described via chlorosulfonation, catalytic Halex-fluorination, and desulfination of 1,3-dichlorobenzene and 2,6-dichlorotoluene.

Details

ISSN :
00221139
Volume :
101
Database :
OpenAIRE
Journal :
Journal of Fluorine Chemistry
Accession number :
edsair.doi...........159ac2fd326c17a39415e6bfdfe28478
Full Text :
https://doi.org/10.1016/s0022-1139(99)00195-5