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Formal total synthesis of (+)-stemoamide

Authors :
Manoj B. Uphade
Kavirayani R. Prasad
Source :
Tetrahedron. 76:131623
Publication Year :
2020
Publisher :
Elsevier BV, 2020.

Abstract

Formal total synthesis of (+)-stemoamide is accomplished from 5-benzyloxypentanal. Key transformation in the synthesis is the conjugate addition of aza-allylanion obtained from allyl amine to an unsaturated ester.

Details

ISSN :
00404020
Volume :
76
Database :
OpenAIRE
Journal :
Tetrahedron
Accession number :
edsair.doi...........17997e63f004f98ee88170f3f0e4657f
Full Text :
https://doi.org/10.1016/j.tet.2020.131623